Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methylphenyl)-2-methylcyclopropyl]ethylidene}aminooxymethyl)phenyl]-2-[(E)-methoxyimino]acetate
نویسندگان
چکیده
The title compound, C(24)H(27)FN(2)O(4), is an important inter-mediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclo-propane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoro-methyl-phenyl group adopts a trans configuration with respect to the remainder of the mol-ecule, and its mean plane forms a dihedral angle of 56.1 (1)° with the plane of the cyclo-propane ring.
منابع مشابه
1-(4-Methylphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole
In the title compound, C29H19F3N2, the tetra-cyclic ring system is essentially planar [maximum deviation from the best plane = 0.076 (1) Å] and makes dihedral angles of 78.10 (5) and 33.71 (4)° with the methyl-phenyl and fluoro-phenyl rings, respectively. An intra-molecular C-H⋯π inter-action occurs. In the crystal, pairs of C-H⋯π inter-actions link inversion-related mol-ecules.
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The title mol-ecule, C(11)H(14)N(2)O(2), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 7.61 (16)°. In the crystal structure, mol-ecules are linked into centrosymmetric dimers by N-H⋯O hydrogen bonds and the dimers are linked together by C-H⋯π inter-actions.
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In the title compound, C28H24F6N2O3, the mean plane of the central pyrazoline ring forms dihedral angles of 2.08 (9) and 69.02 (16)° with the 2-benz-yloxy-6-hy-droxy-4-methyl-phenyl and 3,5-bis-(tri-fluoro-meth-yl)phenyl rings, respectively. The dihedral angle between the mean planes of the pyrazoline and 3,5-bis-(tri-fluoro-meth-yl)phenyl rings is 68.97 (9)°. An intra-molecular O-H⋯N hydrogen ...
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In the title compound, C(26)H(24)N(4)O(2), the dihedral angles between the central pyrazole ring and the other three benzene rings are 40.02 (3), 77.51 (5) and 55.72 (3)°. A strong intra-molecular N-H⋯O hydrogen bond forms a six-membered ring with an S(6) motif. In the crystal structure, a weak inter-molecular C-H⋯N inter-action with graph-set motif R(2) (2)(8) and C-H⋯O hydrogen bonds link eac...
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In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octa-hedral coordination environment. The two benzothia-zole-2-thiol-ate ligands chelate via their thia-zole N and thiol-ate S atoms while the methyl 2-(2-amino-thia-zol-4-yl)-2-(methoxy-imino)acetate also acts as a chelate ligand binding through the thia-zole and imino N atoms. ...
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